- The primary factor responsible for the formation of porosity in heat-cured acrylic resin dentures is rapid polymerization.
- During the curing process, the acrylic resin undergoes a chemical reaction where the monomer converts into a polymer.
- If this reaction occurs too quickly, it generates excessive heat and causes the release of gaseous by-products trapped within the material.
- These gases form bubbles, leading to porosity within the denture base.

Key points to understand include:
- Rapid polymerization increases the temperature sharply, causing vaporization of the monomer.
- This vaporization results in the formation of gas bubbles that get trapped inside the resin matrix.
- Porosity weakens the mechanical properties of the denture and can affect aesthetics and hygiene.
- Other factors like contamination, incorrect monomer-to-polymer ratio, or inadequate curing temperature can also affect the quality but are not the primary cause of porosity.

Therefore, controlling the polymerization rate by using appropriate curing cycles and temperature protocols is essential to minimize porosity and produce a durable, high-quality denture base.

Reference: Dental Materials: Properties and Manipulation, 11th Edition, Chapter 5 – Acrylic Resins / Page 90-95